Stamping Foil Detail

SECTION I : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Identifier : ESF-F1 , ESF-F2, ESF-F3
General Use : Stamping Metallic Or Non Metallic Foil
Company Contact : Everco Advance Industries Sdn Bhd
TEL: 607-355 116
Fax: 607-355 235
 
SECTION II : HAZARDOUS INGREDIENTS / IDENTITIY INFORMATION

Chemical Name CAS No. Concentration*
Resin 9010-88-2 3~10%
Polyethylene terephthalate 2308-59-9 95~99%
Polyester Mixture 5~25%
Methyl methacrylate 80-62-6 < 0.3%
Aluminium 7429-90-5 Trace
Dye 7433-86-2 Trace

* All concentrations are percent by weight unless ingredient is a gas.
Gas concentrations are in percent by volume.
 
SECTION III: HAZARD IDENTIFICATION

Emergency Overview

Physical State : Roll
Color : Varies with product
Odor : Varies with product

Low hazard for usual industrial or commercial handling by trained personnel.
Under normal conditions of processing and use, exposure to the chemical constituents in this product is unlikely


Potential Health Effects

Inhalation : During curing, the product will release small quantities of irritating vapors.
Eye Contact  : May cause minor irritation on eye contact.
Skin Contact : Prolonged skin contact may cause temporary irritation
Ingestion : Not relevant, due to the form of the product.
Potential Physical : This product is not flammable.
Environment : The environmental hazard of the product is considered to be limited.
 
SECTION IV : FIRST AID MEASURES

Inhalation : Move into fresh air and keep at rest.
Get medical attention if any discomfort continues.
Eye Contact : Flush eyes thoroughly with water for at least 15 minutes.
Get medical attention promptly if symptoms occur after washing.
Skin Contact : Wash contact areas with soap and water. If irritation occurs,
Get medical assistance.
Ingestion : Not likely, due to the form of the product. If ingestion occurs:
Rinse mouth thoroughly. Get medical attention if symptoms occur.
 
SECTION V : FIRE FIGHTING MEASURES

Extinguishing Media : Carbon dioxide or dry powder.
Unsuitable Extinguishing Media : None
Special Fire Fighting Procedures : No Specific Precautions.

Explosion Hazards :
By Heating And Fire, Harmful Vapors or Gases may be formed

Hazaedous Combustion Products :
Carbon Dioxide & Carbon Monxide

Protective Measures :
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
 
SECTION VI : ACCIDENTAL RELEASE MEASURES

Personal Precautions : Avoid any exposure. See Section 8 of the MSDS for Personal Protective Equipment
Spill Cleanup Methods : Shovel up and place in a container for salvage or disposal.
 
SECTION VII : HANDLING AND STORAGE

Handling : All handling to take place in well-ventilated area. Do not breathe fumes produced at elevated temperatures. Observe good industrial hygiene practices.
Storage : Store in a cool, dry place out of direct sunlight.
 
SECTION VIII : EXPOSURE CONTROLS AND PERSONAL ROTECTION

Chemical Name Source Type Exposure Limits
Methyl methacrylate US. ACGIH TLV TWA 50 ppm
Methyl methacrylate US. ACGIH TLV STEL 100 ppm
Methyl methacrylate US. NIOSH Guide IDLH 1000 ppm
Methyl methacrylate US. OSHA Z-1 PEL TWA 100ppm 410mg/m3

Engineering Controls : Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Provide adequate ventilation. In case of inadequate ventilation or when the product is heated,use suitable respiratory equipment with gas filter (type A2). If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to anacceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a programshould be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Use a NIOSH-approved respirator.
Eye Protection : If contact is likely, safety glasses with side shields are recommended.Risk of contact: Wear approved safety goggles.
Hand Protection : Wear protective gloves.
Skin Protection : Risk of contact: Use skin protection
Hygiene Measures : Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking Routinely wash work clothing and protective equipment to remove contaminants.
Environmental Exposure Control : Environmental manager must be informed of all major spillages
 
SECTION IX : EXPOSURE CONTROLS AND PERSONAL ROTECTION

Color : Varies with product
Odor Threshold : No data available
pH : Not Applicable
Freezing Point : No data available
Flash Point : Not Applicable
Flammability (Solid) : No data available
Flammability Limit – Lower (%) : No data available
Vapor Density (Air=1) : Not Applicable
Solubility in Water : Insoluble
Partition Coefficient : No data available
Decomposition Temperature : No data available
Odor : Resin
Physical State : Roll
Melting Point : No data available
Boiling Point : Not Applicable
Evaporation Rate : Not Applicable
Flammability Limit – Upper (%) : No data available
 
SECTION X : STABILITY AND REACTIVITY

Stability : Stable under normal temperature conditions and recommended use.
Conditions to Avoid : Excessive heat.
Incompatible Materials : Strong oxidizing agents. Strong acids.

Hazardous Decomposition Products:

At Elevated Temperatures : Carbon Dioxiode, Carbon Monoxide.
Possibility of Hazardous Reactions : Will not occur.
 
SECTION XI :TOXICOLOGICAL INFORMATION

Specified Substance(s)

Acute Toxicity :    No test data available for the ingredients


Listed Carcinogens

Chemical Name IARC NTP ACGIH
Methyl methacrylate 3 Not Listed A4

IARC : 1 = Carcinogenic to Humans; 2A = Probably Carcinogenic to Humans; 2B = Possibly Carcinogenic to Humans; 3 = Not classifiable as to carcinogenicity to humans;4 = Probably not carcinogenic to humans;Not listed = Not evaluated by IARC

ACGIH  : A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen; A4 = Not classifiable as a human carcinogen; A5 = Not suspected to be a human carcinogen; Not listed = Not evaluated by ACGIH


Product Information

Acute Toxicity : No test data available for the ingredients
Other Acute : No additional adverse health effects noted.
Chronic Toxicity No data available.
 
SECTION XII : ECOLOGICAL INFORMATION

Ecotoxicity : Not expected to be harmful to aquatic organisms.
Mobility : The product is insoluble in water.
Persistence and Degradability  : No data available.
Bioaccumulation Potential  : No data available on bioaccumulation.
 
SECTION XIII : DISPOSAL INFORMATION

General Information : Dispose of waste and residues in accordance with local authority requirements.
Disposal Methods : Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
 
SECTION XIV : TRANSPORT  INFORMATION

DOT : Not regulated.
IATA : Not regulated.
IMDG : Not regulated.
 
SECTION XV : REGULATORY INFORMATION

CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Name RQ
Methyl methacrylate 1000 lbs

SARA Title III
Section 302 Extremely Hazardous Substances

(40 CFR 355, Appendix A) :    Not regulated.

Section 313 Toxic Release Inventory (40 CFR 372):


Chemical CAS-no threshold for other threshold for manufacturing
Methyl methacrylate 80-62-6 10000 lbs 25000 lbs

For reporting purposes : the De Minimis Concentration for a toxic chemical in a mixture is 0.1% for carcinogens as defined in 29 CFR 1910.1200(d)(4) or 1% for others.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention

(40 CFR 68.130) : Not regulated

Clean Water Act Section 311 Hazardous Substances

(40 CFR 117.3)  : Not regulated
Drug Enforcement Act : Not regulated


TSCA Test Rules

TSCA Section 4(a) Final Test Rules & Testing Consent Orders : Not regulated
TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) : Not regulated
TSCA Section TSCA Section 5(e) PMN-Substance Consent Orders : Not regulated
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) : Not regulated


State Regulations

California Safe Drinking Water and Toxic Enforcement Act of 1986 : Not regulated
Massachusetts Right-To-Know List : Not regulated
Michigan Critical Materials List (Act. 451 of 1994) : Not regulated
Minnesota Hazardous Substances List : Not regulated
New Jersey Right-To-Know List : Not regulated
Pennsylvania Right-To-Know List  : Not regulated
Rhode Island Right-To-Know List : Not regulated
 
SECTION XVI : OTHER INFORMATION

Hazard Ratings

TYPE Health Fire Instability Special
NFPA 1 0 0 0

NFRA Rating : 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe
NFPA Label colored diamond code : Blue - Health; Red - Flammability; Yellow - Instability; White - Special Hazard


Hazard Ratings

TYPE Health Flammability Physical Personal Protection
HMIS 1 0 0 E

HMIS Ratings : 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe
HMIS Label : Blue - Health; Red - Flammability; Orange - Physical Hazards; White - Special
Personal Protection ID : E - Safety Glasses, Gloves, Dust Respirator
Issue Date : 2005-7-23

MK Stamping Foil, Inc. provides the information contained herein in good faith. The information is believed to be correct. However it is not all-inclusive and should be used only as a guide. Individuals receiving the information must exercise their independent judgement in determining its appropriateness for a particular purpose. MK Stamping Foil, Inc. shall not be held liable for any damage resulting from handling or from contact with the product listed herein.


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